Removal of boron from aqueous solution using magnetic carbon nanotube improved with tartaric acid
نویسندگان
چکیده
Boron removal capacity of multi-walled carbon nanotubes (MWCNTs) modified with tartaric acid was investigated in this study. Modification of MWCNTs with tartaric acid was confirmed by Boehm surface chemistry method and fourier transform infra-red (FT-IR) spectroscopy. Experiments were performed to determine the adsorption isotherm and adsorption thermodynamic parameters of boron adsorption on tartaric acid modified MWCNTs (TA-MWCNTs). The effect of variables including initial pH, dosage of adsorbent, contact time and temperature was investigated. Analysis of data showed that adsorption equilibrium could be better described by Freundlich isotherm and the maximum adsorption capacities obtained at the pH of 6.0 was 1.97 mg/g. The estimated thermodynamic values of free energy (ΔG°), entropy (ΔS°) and enthalpy (ΔH°) indicated a spontaneous and an endothermic process. Furthermore, the TA-MWCNTs was magnetized for separation of boron-contaminated adsorbent from aqueous solution by applying magnetic field. The results showed that magnetic TA-MWCNTs particles were separated effectively after adsorption from contaminated water.
منابع مشابه
Magnetic Multi-Walled Carbon Nanotube as an Adsorbent for Toluidine Blue O Removal from Aqueous Solution
Toluidine Blue O (TBO) is a cationic dye which is extensively used in the industries. In the present paper a simple and efficient wet chemical method was introduced for removal of TBO from waste aqueous solution. Magnetic multi-walled carbon nanotubes were synthesized using commercially available multi-wall carbon nanotubes and magnetic iron oxide nanoparticles which were examined for removal o...
متن کاملComparing activated carbon and magnetic activated carbon in removal of linear alkylbenzene sulfonate from aqueous solution by heterogeneous catalytic ozonation process
Activated carbon from pine cone (PCAC) was used as a precursor to prepare Fe3O4/magnetic activated carbon (MPCAC). Here, the removal of linear alkylbenzene sulfonate (LAS) was studied using catalytic ozonation process (COP) in exposure to MPCAC. Subsequently, it was compared with PCAC. Moreover, the effects of solution's initial pH, catalyst dosage, and the time of ozonati...
متن کاملMesoporous Carbon Modified with Iron Oxide Based Magnetic Nanomaterials for Removal of Malachite Green Dye From Aqueous Solution
Mesoporous carbon (CMK-3) modified with Fe3O4 nanoparticles has been successfully synthesized and characterized by powder X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscope (SEM) and transmission electron microscopy (TEM).The results depict that the synthesized Fe-CMK-3 preserved the ordered mesoporous structure of CMK-3, and magnetic species were dispersed insi...
متن کاملMulti-walled Carbon Nanotube-CO-NH(CH2)2NH-SO3H: A New Adsorbent for Removal of Methylene Blue from Aqueous Media
In this study, Multi-walled carbon nanotube-CO-NH(CH2)2NH-SO3H was prepared through the functionalization of commercial multi-walled carbon nanotubes in three steps and then it was characterized using Fourier Transform Infrared Spectroscopy (FTIR) and Transmission Electron Microscopy (TEM). In addition, the adsorption of Methylene Blue was investigated by using these nanotubes. In order to remo...
متن کاملAcid violet 17 Dye Decolorization by Multi-walled Carbon Nanotubes from Aqueous Solution
Background: Dyes can cause many problems in environment. Therefore, removal of these contaminants before discharging wastewater to environment can reduce the environmental hazards. Adsorption is one of the usual processes for decolorizing from wastewater. Nanotubes are new adsorbents that can adsorb different compounds. This work aimed to investigate Acid violet 17 dye removal by adsorption usi...
متن کامل